Absolute
viscosity:
An
observation of liquid’s rate of flow under pressure applied
to neutralize density’s influence. This property, sometimes
called dynamic viscosity, converts to kinematical viscosity
by division. With density ex-pressed in grams/cm, centistokes
the units of kinematical viscosity, and centipoises the
units of absolute viscosity.
Centipoises/density
= centistokes
Activity:
The
level of catalyst’s ability to do its work. The scale descends
from fresh (full capacity right from the box or rejuvenator)
to spent (coated, poisoned, or other wise neutralized.)
Actual
specifications:
The
quality reports on a specific parcel of fuel or feedstock.
Such specifications do not constitute guarantees on the
oil unless the seller says so. But they give a good description
of the product available aboard a vessel or in a storage
tank.
AFRA:
Average
Freight Rate Assessments. A monthly estimate of tanker rates
issued by London tanker brokers, AFRA, quoted on a Worldscale
basis, assists large oil companies’ internal accounting,
provides a freight element for some netback deals, and serves
other purposes somewhat removed for the daily tanker business.
Air
Draft:
The
distance between the surface of navigable water, such as
a channel, and the lowest point on some obstruction above
it, a bridge for instance. A ship cannot use a waterway
if it needs more vertical clearance than available. This
consideration prevents certain tankers from reaching some
terminals.
Aliphatic:
Straight
or branched chain carbon-based compounds. Hydrocarbons which
lack carbon-ring structures. Aliphatics includes three kinds
of molecules: paraffins, olefins, and a particularly reactive
sort called acetylenes, which contain triple carbon-carbon
bonds.
Alkylate:
A
high-quality motor gasoline component made by combining
isobutene and propylene or butylene. Butylene alkylate has
a particularly high motor octane rating which suits it well
for blending lead-free grades of automobile fuel and aviation
gasoline. Both butylene and propylene alkylate boil fairly
low in the gasoline range. This characteristic makes them
good “front-end” octane.
Alkylation
unit:
A
piece of refining equipment that combines isobutane and
an olefinic stream, usually butylene-rich, to make motor
alkylate.
Aniline
point:
A
specification, quoted in degree Fahrenheit in the USA and
Centigrade elsewhere, which reports the aromatics content
of a hydrocarbon mixture. This quality consideration indicates
the susceptibility of a vacuum gasoil to catalytic cracking
because paraffins crack well, but aromatics do not. The
higher the temperature the better, since higher temperatures
mean less aromatics, hence more paraffins.
Antiknock
index:
The
average of a motor gasoline’s or blending component’s RON
and MON (RON + MON)/2, sometimes written (R + M)/2.
API
Degrees (`API):
The
units of API’s density scale.
See below.
API
Gravity:
A
density scale expressed in API degrees. The following formula
relates this representation of density to specific gravity:
API
= (141.5/specific gravity @ 60`F)-131.5.
AR:
American rate.
Tanker hire prices according to the American Tanker Rate
Schedule. This system applies to voyages which begin and
end in US ports. US law (the Jones Act) allows only US-flag
ships in this domestic service.
Aromatics:
A
family of hydrocarbons characterized by a single or multiple
ring structure containing unsaturated carbon-carbon bonds.
Common aromatics which boil in the gasoline range (benzene,
toluene, and xylenes, in particular) have a very high octane
rating. Reformers produce high octane blend-stock by making
aromatics. The "A" in PONA and N+A stands for
aromatics.
Ash:
Carbonaceous
residue produced by burning crude oil and petroleum products.
The industry tests fuels and other hydrocarbon mixtures
in order to determine how much of this combustion by-product
will form in ordinary use of its products. Refiners and
others also use ash yield to deduce the presence of metallic
soaps, abrasive solids, and other ash-causing contaminents
in hydrocarbon mixtures.
Asphalt:
A
mixture of heavy carbon-based compounds containing a high
percentage of multiple-ring aromatics, many of them involving
sulfur, nitrogen, and oxygen atoms. Some folks use the word,
asphalt, interchangeably with bitumen,
the name of its characteristic constituent.
Asphalt
cement:
A
derivative, nearly or completely solid at room temperature,
of certain crude oils. This black, tarry material usually
comes from vacuum residue. It has several industrial applications.
Pavers heat it to liquid form and mix in gravel to make
road surface materials called blacktop, macadam, tarmac,
or "asphalt". Builders use it to make and join
bricks, to coat roofs, and to form shingles. It glues together
various manufactured goods.
Asphaltenes:
Complex
molecules which reveal their ring-structures by dissolving
in aromatic liquids but not in paraffins. These compounds
may influence the burning and blending characteristics of
residual oils, if present in sufficient concentrations.
They contribute to the high melting temperature and adhesion
of bitumen and
asphalt cement.
Assay:
An
elaborate laboratory report describing in detail the quality
of grades of crude oil. The data presented includes, among
other items, density, sulfur, naphthenicity, pour point,
viscosity, distillation, and information on the quality
of individual fractions. They tell a refiner what products
he can make from a specific crude.
ASTM:
American
Society for Testing and Materials. An organization which
determines and publishes consensus standards of suitability
and quality for a wide variety of materials including petroleum
and refined products. ASTM develops and endorses methods
of testing hydrocarbons properties as well as definitive
specifications for such classes of refined product as fuel
oils, aviation kerosene, burning kerosene, and motor gasoline.
Atmos:
Abbreviation
of atmospheric-pressure distillation, as in atmos bottoms
and atmos gasoil.
Atmospheric
distillation:
A
technique for separating hydrocarbon mixtures which uses
distillation apparatus operated at atmospheric pressure.
Generally, the industry specifies ambient pressure to distinguish
products of crude distillers, atmospheric fractions, from
the products of vacuum flashers which, as the name implies
distill atmospheric residue in a partial vacuum.
Atmospheric
gasoil:
The
heaviest product boiled by a crude distillation unit operating
at atmospheric pressure. This fraction ordinarily sells
as distillate fuel oil, either in pure form or blended with
cracked stocks. In blends atmospheric gasoil, often abbreviated
AGO, usually serves as the premium quality component used
to lift lesser streams to the standards of saleable furnace
oil or diesel engine fuel. Certain ethylene plants, called
heavy oil crackers, can take AGO as feedstock.
Atmospheric
residue:
The
portion of crude oil taken as a bottoms product in a crude
distillation unit which operates at atmospheric pressure
under several other names apply to this product including
atmos (atmospheric) reside, atmos bottoms, atmospheric fuel
oil long reside, straight-run heavy fuel oil and topped
crude.
Availability:
A
quantity of crude or product a supplier could sell.
Aviation
gasoline:
High-grade
motor fuel blended to meet the requirements of piston-type
aero plane engines. This specialty product differs in all
critical respects from aviation turbine fuel (jet).
Aviation
turbine fuel (ATF):
The
fuel burned by aero planes jet engines. Civilian aircrafts
consumes a kerosene-range product variously known as jet
kero, jet
A-1, avtur, DERD-2494,
and JP1. Warplanes needed special fuels.
Two military grades, JP-4
and JP-5 fall
within the common notion of AFT.
Avgas:
Familiar
designation of aviation gasoline.
Backhaul:
A
tanker's revenue-producing return voyage. Some ships shuttle
between two tankers ports. They travel in one direction
as dictated by normal oil flow patterns or refining system's
needs. Often, they have no natural employment from when
they discharge to their port of origin where another load
awaits. They would like to find a cargo to pay their costs
on this return trip. Otherwise, they must return in ballast.
Charters often relet
ships at bargain back haul rates for these voyages. They
prefer some income to none.
Ballast:
Water
taken aboard a vessel to increase its draft, steady its
motion, correct its trim, or otherwise make it more seaworthy
when sailing without cargo. The trade uses this word to
describe repositioning voyages or empty backhauls
forced on ship. Hence, phrases appear like "ballasting
Trans-Atlantic"
Barge
lots:
Quantities
of petroleum product accommodated in the sizes of barges
in common use in a particular area. This term usually applies
to small (less than cargo-size) volumes of product intended
for regional distribution. On the US Gulf Coast, for instance,
petroleum products barges typically range from 10,000 to
50,000 barrels. On the Rhine, barges typically carry lots
as large as 1,000 tons.
Base
stock:
A
hydrocarbon mixture which makes up much of the volume of
a gasoline blend. Usually such stocks have properties not
too far removed from finished fuel because the minor components
have to bring the entire blend within accepted limits of
gasoline quality. Base stocks in today's US motor gasoline
include cat gasoline, reformate, and alkylate.
Beam:
The
breadth of a ship at its widest point.
Benzene:
The
simplest aromatic.
This unsaturated six-carbon ring forms the basis of a whole
class of compounds. The coal processing business first produced
benzene in commercial quantities. This source still provides
some of the material on the market. But refinery and petrochemical
plant reformers, toluene hydrodealkylators, and steam crackers
now make most of the supply. The products of benzene range
from egg cartons to pesticides to nylon stockings.
Bitumen:
Mineral
pitch rich in asphaltenes
and other complex, high-molecular-weight molecules. These
mixtures of heavy hydrocarbons and resins form the base
of, and impart adhesive, semi-solid consistency to asphalt
cement and tar.
Blender:
Someone
or some organization which combines various components to
produce motor gasoline. The term may accurately apply to
refiners for they blend motor fuel from blendstock they
produce or purchase. In many cases, however, the word designates
gasoline makers who do not refine any crude oil and distinguishes
them from the "refiners" who do.
Blendstock:
A
component combined with other materials to produce a finished
petroleum product. The term applies most frequently to motor
gasoline ingredients.
Boiling
range:
The
temperature spread between the points where a material starts
and finishes evaporating. This term has an abstract usage-
naphtha-range,
for example. It also has a specific one, such as "naphtha
with a 140-350 F range."
Bond:
Linkage
between atoms which holds together molecules. The basic
bond involves two atoms connected by a pair of shared electrons.
A double bond requires linkage by two pairs (four electrons).
A triple bond puts six electrons between two atoms.
Bottoms:
Unvaporized
material drawn from the lowest point of a fractionation
column.
Bromine
number:
A
measure of the olefins content of a hydrocarbon mixture.
In the petroleum intermediates trade, it serves primarily
to indicate the presence of cracked stock in a cargo or
stream. California air pollution laws also make it an important
specification for motor gasoline and blendstocks offered
in Los Angeles. As a rule-of-thumb, a mixture's bromine
number equals roughly twice its olefin
content.
BTX:
An
abbreviation for benzene, toluene, and xylene.
BTX
extraction:
A
solvent recovery process for capturing benzene, toluene,
and xylenes from refinery and petrochemical plant process
streams (reformate
and pyrolysis gasoline.)
Bunkers:
Fuel,
usually residue grades, burned by ships' main engines. The
most familiar kind, called bunker C may contain a high concentration
of sulfur and have a high specific gravity but must meet
a viscosity specification which assures free flow at the
temperatures vessels' fuel systems can maintain.
Burning
kerosene:
Kerosene
intended for use as domestic stove lamp fuel.
Butadiene:
A
four-carbon olefin.
More precisely, a di-olefin because the molecule has two
double bonds. Synthetic rubber production consumes much
of the butadiene supply. Smaller amounts find an outlet
in high-strength resins manufacturing.
Buy/sell:
A
swap in which, for accounting purposes or other reasons,
company A sells a parcel to company B while B sells a second
parcel to A. Each party buys one and sells another.
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Carbon
residue:
The
solid, impure carbon deposits (coke) left behind by burned
hydrocarbon fuels. The industry uses two tests, Conradson
carbon (Con Carbon)
and Ramsbottom
carbon to measure oils'
tendency to form such solids.
Catalytic
cracker:
These
refinery units, also widely known as cat crackers and FCC's
(for fluid catalytic crackers) or FCCU's, convert heavy
distillate, most commonly vacuum gasoil, to lighter fractions.
Refiners use them, basically, to break molecules which boil
in the heavy distillate range to shorter, more volatile
hydrocarbon chains suitable for making motor gasoline.
Catfeed:
The
charge fed to a catalytic cracker. Common usage generally
restricts this term to describing vacuum gasoils.
Cat
gasoline:
The
motor fuel-blending component produced by catalytic cracking
units.
Cat
naphtha:
See
CAT
GASOLINE.
Some refiners could, if their markets made it desirable,
hydrotreat cat gasoline to make a naphtha suitable for some
use other than motor fuel blending, such as steam cracker
feedstock.
Centigrade
degrees (C):
Also
known as Celsius degrees. A temperature scale according
to which water boils at 100 and freezes at 0. Centigrade,
or Celsius, degrees convert to Fahrenheit degrees by the
following formula: (C x 1.8) + 32=F.
Centistoke:
The
unit, commonly abbreviated cSt, of kinematic
viscosity which
reports a liquid's resistance to flow in terms of its measured
viscosity divided by its density.
Cetane
index (CI):
An
estimated diesel fuel performance rating which relies on
samples' API gravity and mid-point
CI=-420.34
+ 0.016G2 + 0192G log M
+ 65.01 (LOG M)2-0.0001809M2
where G= API gravity and M=mid-point in F
Cetane
number:
A
performance indicator for diesel fuel analogous to the octane
rating applied to gasolines. The more paraffinic the gasoil,
the higher its cetane number.
Cetan
rating:
See
CETANE
NUMBER.
Chains:
This
term has a chemical and a commercial usage in the oil business.
It describes the strands of carbon atoms (carbon chains)
fundamental to hydrocarbon molecules. It also serves as
a designation for the strings of transactions assembled
to settle a period's business in unregulated paper commodities
like Russian gasoil.
Charge:
See
FEEDSTOCK.
Charter
party:
A
document in which a ship owner and a Charterer state their
agreement to terms for carriage of cargo.
Charterer:
The
party who contracts for use of a ship. He can do so for
a voyage, a spot
charter, or a period, a time-charter.
Chemical
Carrier:
See
PARCEL
TANKER.
Chlorides:
Chlorine-containing
compounds. The oil trade pays most attention to these substances
when discussing naphtha. Reformers need a specific amount
of chloride on their catalyst to perform properly, any more
or any less amounts to poison. Naphtha feedstock containing
any significant amount of chlorides upsets the delicate
balance and reduces reformat yield.